Linear and nonlinear optical properties of ferroelectric BaMgF4 and BaZnF4

Abstract
These first measurements of the nonlinear optical properties of fluorides (BaMgF4 and BaZnF4) show these air‐stable compounds to be noncritically phase matchable at room temperature for a 1.06‐μ pump. The highly ionic compounds are also quite resistant to optical damage (∼109 W/cm2). The materials should find applications as frequency doublers in cases where spatial power distribution makes crystals with walk off less desirable and/or cases where high pump powers require crystals which are resistent to damage.