Probing the Surface Area of a Cement-Based Material by Nuclear Magnetic Relaxation Dispersion

Abstract

We show how nuclear magnetic spin-lattice relaxation dispersion of ${}^1\mathrm{H}$ water can provide a direct reliable value of the specific surface area of a cement-based material. The remarkable features of the relaxation dispersion support an interpretation in terms of coupled solid-liquid relaxation at pore interfaces, surface diffusion, and nuclear paramagnetic relaxation. The measurement is sufficiently fast to be applied continuously during the progressive hydration and setting of the material. This method is relevant to other chemically reactive porous media in chemical engineering and oil recovery.