Peroxid‐induzierte thioladdition an polybutadien
- 1 January 1995
- journal article
- research article
- Published by Wiley in Die Angewandte Makromolekulare Chemie
- Vol. 224 (1), 125-131
- https://doi.org/10.1002/apmc.1995.052240113
Abstract
Die radikalische Addition von 1‐Octanthiol oder 3‐(Trimethoxysily)‐1‐propanthiol an die 1,2‐ bzw. 1,4‐cis‐Doppelbindungen des Polybutadiens erfolgt redox‐induziert mit Dibenzoylperoxid (DBPO) bei Raumtemperatur ohne nachweisbare Nebenreaktionen. Trans‐konfigurierte Doppelbindungen reagieren unter gleichen Bedingungen nicht. Die Molmassenverteilung der Additionsprodukte ist ähnlich eng wie die des reinen Polybutadiens.This publication has 14 references indexed in Scilit:
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