Cyanide-bridged Fe(iii)–Co(ii) bis double zigzag chains with a slow relaxation of the magnetisation
- 27 June 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 15,p. 1850-1851
- https://doi.org/10.1039/b302182n
Abstract
Reaction of [FeIII(bipy)(CN)4]− with fully solvated MII cations [M = Co (1) and Mn (2)] produces the isostructural bis double zigzag chains [[FeIII(bipy)(CN)4]2MII(H2O)]·MeCN·½H2O; 1 exhibits intrachain ferromagnetic and interchain antiferromagnetic couplings, slow magnetic relaxation and hysteresis effects.Keywords
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