Kinetics of the Difluoromethylene—Nitric Oxide Reaction. I
- 1 May 1967
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 46 (9), 3663-3668
- https://doi.org/10.1063/1.1841271
Abstract
Evidence from mass spectra and ultraviolet‐light absorption behind shock waves indicates a reversible reaction between difluoromethylene and nitric oxide. Above 2500°K the reaction proceeds further to equilibrium by and In the temperature interval 1600°—2500°K, oscillogram records of CF2 uv absorption are reduced in terms of [1,1′] by the rate law with and From the ratio k1/k1′, the heat of reaction [1] is found to be 4.6 kcal/mole, yielding a heat of formation of the CF2NO radical equal to −15.7 kcal/mole.
Keywords
This publication has 11 references indexed in Scilit:
- Mass-Spectrometer and uv Absorption Study of CHF3 Decomposition behind Shock WavesThe Journal of Chemical Physics, 1966
- Kinetics and Equilibria of the Difluorocarbene Radical Decomposition Behind Shock WavesThe Journal of Chemical Physics, 1966
- Photolysis of Trifluoroiodomethane in the Presence of Oxygen and Nitric Oxide1The Journal of Physical Chemistry, 1966
- Decomposition and Oxidation of C2F4 Behind Shock WavesThe Journal of Chemical Physics, 1965
- Kinetics of some reactions of nitrosoalkanesTransactions of the Faraday Society, 1965
- Mechanism of the Low-Temperature Scavenging of Methyl-d3 Radicals by Nitric OxideJournal of the American Chemical Society, 1963
- A Kinetic Study of the Mechanism of Nitrosomethane Formation and Decay in the Photolysis of Azomethane-Nitric Oxide MixturesJournal of the American Chemical Society, 1960
- A Study of the Methyl-Oxygen and the Methyl-Nitric Oxide Reactions by Flash Photolysis1Journal of the American Chemical Society, 1959
- The photochemical decomposition of methyl iodide in presence of nitric oxide - II. Reactions of nitrosomethaneProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences, 1959
- The Reaction of Nitric Oxide with IsobutyleneJournal of the American Chemical Society, 1957