Polycrystalline Zn3P2 Schottky barrier solar cells

Abstract
Energy conversion efficiencies as high as 5.96% are reported on polycrystalline transparent magnesium Zn3P2 diodes, 0.7 cm2 in area, tested under simulated AM1 illumination. The transparent Mg films with low sheet resistivities are obtained by dc sputtering. The effective minority‐carrier diffusion length in Zn3P2 is estimated from spectral response measurements and correlates well with the measured short‐circuit current. Loss analysis of the present cells shows a practical upper limit of 9% in conversion efficiency.