Dimeric antimony complexes capturing dimethylamine as a neutral donor; syntheses and structural characterisation of [SbCl2(NHMe2)(µ-OEt)]2and [SbCl(NHMe2)(µ-NBut)]2
- 1 January 1994
- journal article
- Published by Royal Society of Chemistry (RSC) in J. Chem. Soc., Dalton Trans.
- No. 9,p. 1479-1482
- https://doi.org/10.1039/dt9940001479
Abstract
The two dimeric antimony complexes, [SbCl2(NHMe2)(µ-OEt)]2 and [SbCl(NHMe2)(µ-NBut)]2 have been synthesised by the reaction of SbClx(NMe2)3–x with EtOH (x= 2) or NH2Bu2(x= 1) respectively; both complexes exhibit the co-ordination of a dimethylamine ligand to antimony and intricate intermolecular association in the solid state.Keywords
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