Concurrent Ion—Molecule Reactions. I. Reactions in X—CD4 Mixtures
- 15 December 1965
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 43 (12), 4201-4206
- https://doi.org/10.1063/1.1696677
Abstract
A ratio‐plot method, whereby the contribution of concurrent ion—molecule reactions to the same product ion may be estimated, has been applied to the study of the formation of the XD+ ion in X—CD4 mixtures for X=CO, N2, and CO2. It is shown that XD+ is formed by both deuteron transfer from CD4+ and by deuterium atom abstraction by X+. The cross sections for the individual reactions have been determined and compared with theory.Keywords
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