Electronic states of a substitutional chromium impurity in GaAs
- 15 August 1979
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 20 (4), 1527-1537
- https://doi.org/10.1103/physrevb.20.1527
Abstract
The scattered-wave cluster method has been used to investigate the electronic properties associated with various charge configurations of a substitutional chromium impurity in GaAs. The usual spin-restricted formalism is found to provide an inadequate treatment of the strong electron-electron interactions between the -like electrons associated with the chromium impurity and leads to a poor description of the resulting electronic states. Two methods of improving the treatment of the impurity electron-electron interactions are porposed and investigated. In the first approach the spin-polarized electronic states of the various clusters are calculated using a spin-unrestricted formalism. This leads to different energy spectra for electrons of different spin and consequently incorporates some of the broad features of the true many-electron multiplet structure in what is essentially a single-electron description. The second approach consists in treating the electron-electron interactions as a perturbation on the single-particle cluster states obtained from the spin-restricted calculations. The many-electron crystal-field term states are then calculated using a modification of the standard crystal-field theory in the strong-field coupling limit. Both of these approaches are applied to the study of the chromium impurity in the and charge configurations, and the results are compared and discussed.
Keywords
This publication has 15 references indexed in Scilit:
- Deep centre photoluminescence spectra of GaAs(Cr, Si)Journal of Physics C: Solid State Physics, 1978
- Experimental verification of Cr2+ models of photoluminescent transitions in GaAs:Cr and AlxGa1−xAs:Cr single crystalsSolid State Communications, 1978
- EPR of() in gallium arsenide: Jahn-Teller distortion and photoinduced charge conversionPhysical Review B, 1977
- Electronic states of simple-transition-metal impurities in siliconPhysical Review B, 1977
- EPR ofin GaAs—evidence for strong Jahn-Teller effectsPhysical Review B, 1977
- Deep traps in semi-insulating GaAs: Cr revealed by photo-sensitive ESRSolid State Communications, 1976
- Photoluminescence from deep centers in GaAsSolid State Communications, 1976
- Photoluminescence of the Cr accepotr in boat-grown and LPE GaAsJournal of Applied Physics, 1976
- Simple model of multiple charge states of transition-metal impurities in semiconductorsPhysical Review B, 1976
- Chemical Bonding of a Molecular Transition-Metal Ion in a Crystalline EnvironmentPhysical Review B, 1972