Adsorption (co‐precipitation) of trace metals at natural concentrations on hydrous ferric oxide in lake water samples

Abstract
Adsorption (co‐precipitation) of Ca, Cd, Cu, Ni, Pb on hydrous ferric oxide (HFO) has been investigated under natural conditions. Ferrous iron (ca 6.8 × 10−5 M) present in samples of anoxic lake water was oxidised under controlled conditions to form insoluble HFO. Adsorption of metals at their natural concentrations (10−9‐10−8M; Ca 4 × 10−4M) was determined in the pH range pH 6.5 ‐ 8.5. A large fraction of the Cd (>80%), Cu (ca 50%) and Pb (ca 60%), but not Ni (< 20–30%) and Ca (ca 1%), was adsorbed.