Distribution of final states resulting from the autoionization of the Σg1(2pσu2) states of H2 and D2
- 1 June 1974
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 60 (11), 4358-4361
- https://doi.org/10.1063/1.1680911
Abstract
Using a simple classical model, we calculate the distribution of final states resulting from the autoionization of the state of H2(D2) to the 2Σg(1sσg) state of . The population of vibrational levels differs markedly from that predicted by the Franck‐Condon principle for direct ionization. The calculated kinetic energy distributions of H+ and D+ have maxima at threshold (Ekin=0). The probability of forming dissociated products is smaller for D2 than H2.
Keywords
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