Efficient Removal of Cr(VI) from Aqueous Solution with Fe@Fe2O3 Core−Shell Nanowires

Abstract

The batch removal of Cr(VI) from simulated wastewater with [email protected]₂O₃ core−shell nanowires (FCSNs) was investigated in this study. It was found that each gram of the FCSNs could remove 7.78 mg of Cr(VI) from simulated wastewater containing 8.0 mg L⁻¹ of Cr(VI) with an initial pH of 6.5 at room temperature. The Freundlich adsorption isotherm was applicable to describe the removal processes. Kinetics of the Cr(VI) removal was found to follow pseudo-second-order rate equation. Furthermore, the as-prepared and Cr(VI)-adsorbed FCSNs were carefully examined by scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), Fourier transform infrared spectroscopy (FT-IR), and X-ray photoelectron spectroscopic analysis (XPS). The characterization results suggested that the adsorbed Cr(VI) was partially reduced to Cr(III) in Cr₂O₃/Cr(OH)₃ on the FCSNs. The possible mechanism of removal of Cr(VI) on FCSNs was proposed, which involved the dominant Cr(VI) adsorption, followed by the partial reduction of Cr(VI) to Cr(III) (chromium(III) oxyhydroides) on the surface of FCSNs. These [email protected]₂O₃ core−shell nanowires with high specific surface area and strong magnetic property are very attractive for the removal of Cr(VI) from wastewater.