Spatially resolved second-harmonic-generation investigations of proton-induced refractive-index changes in LiNbO3

Abstract
Doping profiles generated by electric‐field‐assisted proton diffusion in LiNbO3 bulk material are investigated, spatially resolved by absorption and by second‐harmonic‐generation measurements. The results allow a direct correlation of the refractive‐index changes with the local proton density. It is shown that protons are the only mobile ions under the experimental conditions applied (600 °C, 100 V/cm), whereas lithium ions do not move under these conditions. Similar results were obtained for samples doped with deuterium.