INFLUENCE OF IMPURITIES ON Si (111) SURFACE STRUCTURES

Abstract
In situ LEED studies of the homoepitaxial growth of Si (111) films by uhv sublimation indicate that the surface structures which develop are strongly influenced by the metallic impurity content of the silicon substrates, as judged from minority carrier lifetimes. The development of the familiar Si (111)−7×7 LEED pattern at a given annealing or homoepitaxial growth temperature appears to be favored on silicon substrates possessing low lifetimes. Experiments where Fe is introduced prior to annealing and film growth on high‐lifetime silicon suggest that this impurity species can lead to the formation of the Si (111)−7×7 surface structure.