Tunneling and Exchange in Quantum Solids
- 5 December 1969
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 188 (1), 445-468
- https://doi.org/10.1103/physrev.188.445
Abstract
Pairs of atoms in solid bcc have spatially symmetric or antisymmetric wave functions which correspond to energies and , . The energy difference is due to a tunneling process and an interaction process. The effect of these two processes can be simulated by adding to the Hamiltonian of the solid an exchange Hamiltonian, where is a sum (due to the tunneling process) and (due to the interaction process). A theory of the magnitude and sign of and is given. We find and . Using quite general arguments, we show that . The exchange in bcc solid is antiferromagnetic. Evaluation of the formulas for and using the ground-state wave function of Guyer and Sarkissian leads to , in good agreement with experiment.
This publication has 18 references indexed in Scilit:
- A contribution to the theory of quantum solidsSolid State Communications, 1969
- Exchange in CrystallineHe3Physical Review Letters, 1968
- Towards a Quantum Many-Body Theory of Lattice Dynamics. II. Collective Fluctuation ApproximationPhysical Review B, 1968
- Critique of the Saunders Theory of Solidat 0°KPhysical Review B, 1968
- Nuclear-Spin Exchange Interaction in Solid 3HeJournal of Applied Physics, 1968
- Theory of Quantum Crystals. II. Three-Body Term in the Cluster ExpansionPhysical Review B, 1967
- Theory of Quantum CrystalsPhysical Review B, 1966
- Exchange in solid 3He and the Heisenberg HamiltonianProceedings of the Physical Society, 1965
- Ground State of SolidPhysical Review B, 1962
- Theory of SolidPhysical Review B, 1960