Abstract
Recent calculations of Thorson and co-workers for H+ + H ionization mechanisms and the Briggs-Macek scaling law for K-vacancy production in symmetric heavy-ion collisions are used to show the following: (1) If Fano-Lichten-type electron promotion is inhibited because of the absence of a 2p vacancy, i.e., if Z>10, K vacancies in symmetric collisions are produced mainly by 2pσ electron excitation to vacant bound and unbound molecular-orbital states. (2) The direct 1sσ excitation cross section to vacant bound and unbound states can be obtained experimentally. The relationship between atomic and molecular-orbital Coulomb excitation cross sections is discussed.