Vibrational and Rotational Effects on the Nuclear Quadrupole Coupling Constants in Hydrogen, Deuterium, and Tritium Halides
- 1 July 1967
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 47 (1), 109-113
- https://doi.org/10.1063/1.1711832
Abstract
The differences of the nuclear quadrupole coupling constants in hydrogen, deuterium, and tritium halides have been studied by considering effects of vibration and rotation on the field gradient. The variation of the coupling constant can be explained by the change in size of the molecule arising from the substitution of hydrogen by deuterium or tritium.Keywords
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