Solvent-Tuned Azido-Bridged Co2+ Layers: Square, Honeycomb, and Kagomé
- 24 December 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 128 (3), 674-675
- https://doi.org/10.1021/ja055725n
Abstract
Three azido-bridged Co2+ complexes with square, honeycomb, and Kagomé layered structures were synthesized and structurally characterized. Crystallization solvents are found to be critical in generating the observed topologies. These structurally related complexes are of significance in studying two-dimensional antiferromagnetism and geometric frustration.Keywords
This publication has 18 references indexed in Scilit:
- (EDT-TTF-CONH2)6[Re6Se8(CN)6], a Metallic Kagome-Type Organic−Inorganic Hybrid Compound: Electronic Instability, Molecular Motion, and Charge LocalizationJournal of the American Chemical Society, 2005
- 4-Connected Metal−Organic Assemblies Mediated via Heterochelation and Bridging of Single Metal Ions: Kagomé Lattice and the M6L12 OctahedronJournal of the American Chemical Society, 2005
- Spin Frustration in 2D Kagomé Lattices: A Problem for Inorganic Synthetic ChemistryChemistry – A European Journal, 2004
- An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2‘-bithiazoline)(N3)2]nJournal of the American Chemical Society, 2003
- A Topology Paradigm for Metal‐Organic ZeolitesAngewandte Chemie International Edition, 2003
- Symmetry breaking due to Dzyaloshinsky-Moriya interactions in the kagomé latticePhysical Review B, 2002
- Magnetic structure of thekagomélattice antiferromagnet potassium jarositePhysical Review B, 2000
- Magnetic properties of pure and diamagnetically doped jarosites: Modelkagoméantiferromagnets with variable coverage of the magnetic latticePhysical Review B, 2000
- Variable magnetic interactions in an organic radical system of (m-N-methylpyridinium α-nitronyl nitroxide)⋅: A possiblekagoméantiferromagnetPhysical Review B, 1994
- Possible Néel orderings of the Kagomé antiferromagnetPhysical Review B, 1992