An Azide-Bridged Homospin Single-Chain Magnet: [Co(2,2‘-bithiazoline)(N3)2]n
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- 29 October 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 125 (46), 13976-13977
- https://doi.org/10.1021/ja0380751
Abstract
A novel end-on azide-bridged homospin 1D chain, Co(bt)(N3)2 (1) (bt = 2,2‘-bithiazoline), is constructed by sharing edges of Co(II) distorted octahedrons to form a helix, which shows magnetic hysteresis with steps and slow relaxation below 5−6 K, typical of single-chain magnet behavior.Keywords
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