A Carbon Nanotube-based Sensor for CO2 Monitoring

Abstract

A carbon dioxide (CO₂) sensor is fabricated by depositing a thin layer of a multiwall carbon nanotube (MWNT) – silicon dioxide (SiO₂) composite upon a planar inductorcapacitor resonant circuit. By tracking the resonant frequency of the sensor the complex permittivity of the coating material can be determined. It is shown that the permittivity of MWNTs changes linearly in response to CO₂ concentration, enabling monitoring of ambient CO₂ levels. The passive sensor is remotely monitored with a loop antenna, enabling measurements from within opaque, sealed containers. Experimental results show the response of the sensor is linear, reversible with no hysteresis between increasing and decreasing CO₂ concentrations, and with a response time of approximately 45 s. An array of three such sensors, comprised of an uncoated, SiO₂ coated, and a MWNT-SiO₂ coated sensors is used to self-calibrate the measurement for operation in a variable humidity and temperature environment. Using the sensor array CO₂ levels can be measured in a variable humidity and temperature environment to a ± 3% accuracy.