Near-threshold infrared photodetachment ofAl−: A determination of the electron affinity of aluminum and the range of validity of the Wigner law

Abstract

The relative photodetachment cross section of ${\mathrm{Al}}^{\mathrm{-}}$ has been measured in the wavelength range 2420–2820 nm (0.440–0.512 eV), using a coaxial ion-laser beams apparatus, in which a 2.98-keV ${\mathrm{Al}}^{\mathrm{-}}$ beam is merged with a beam from an F-center laser. The cross-section data near the ${}_{}{}^3{}_{}{}^{}$ ${\mathit{P}}_{0,1,2}$ ${\to }^2$ ${\mathit{P}}_{1/2,3/2}$ photodetachment threshold have been fitted to the Wigner threshold law and to the zero-core-contribution theory of photodetachment. The electron affinity of aluminum was determined to be 0.44094(+0.00066/-0.00048) eV, after correcting the experimental threshold for unresolved fine structure in the ground states of ${\mathrm{Al}}^{\mathrm{-}}$ and Al. The new measurement is in agreement with the best previous measurement (0.441±0.010 eV) and is 20 times more precise. The Wigner law agrees with experiment within a few percent for photon energies within 3% of threshold. A proposed leading correction to the Wigner law is discussed. © 1996 The American Physical Society.