Photoelectron angular distributions from multiphoton ionization of cesium atoms

Abstract

We present both experimental and theoretical studies of resonantly enhanced multiphoton ionization of cesium atoms. Photoelectron angular distributions for two-photon ionization via the one-photon-allowed $7p{}_{}{}^2{}_{}{}^{}P_{\frac{1}{2},\frac{3}{2}}^{}{}_{}{}^{}$ and $8p{}_{}{}^2{}_{}{}^{}P_{\frac{1}{2},\frac{3}{2}}^{}{}_{}{}^{}$ intermediate states and three-photon ionization via the two-photon-allowed $8d{}_{}{}^2{}_{}{}^{}D_{\frac{5}{2},\frac{3}{2}}^{}{}_{}{}^{}$ resonant intermediate states are reported. The photoelectrons are energy analyzed with a spherical-sector electrostatic energy analyzer with an energy resolution of ~ 0.1 eV and angular resolution of ~ ±2°. A straightforward calculation based upon a finestructure scheme gives excellent agreement with the measured angular distributions for the ${}_{}{}^2{}_{}{}^{}P_{\frac{1}{2}}^{}{}_{}{}^{}$ states. The laser pulse duration is comparable to the hyperfine precession period which allows the hyperfine coupling to partially destroy the anisotropy initially produced in the ${}_{}{}^2{}_{}{}^{}P_{\frac{3}{2}}^{}{}_{}{}^{}$ resonant intermediate states. Quantitative calculations including hyperfine coupling take this into account and provide an expression which gives a reasonable fit to the ${}_{}{}^2{}_{}{}^{}P_{\frac{3}{2}}^{}{}_{}{}^{}$ data.