I n s i t u x-ray photoelectron spectroscopic study of GaAs grown by atomic layer epitaxy

Abstract
We carried out an in situ investigation of GaAs grown by atomic layer epitaxy, using an x‐ray photoelectron spectroscopy system combined with a metalorganic vapor phase epitaxial growth chamber, where Ga(CH3)3 and AsH3 were the source gases. It has been proved that Ga(CH3)n molecules (where n=1 or 2) are decomposed into Ga atoms after being adsorbed on the GaAs surface around 500 °C. This means that the self‐limited adsorption of Ga in the atomic layer epitaxy of GaAs can be achieved on the surface where the Ga adsorbate is atomic Ga.