Study of depolarized Rayleigh scattering in liquid benzene derivatives

Abstract

The spectrum of the depolarized Rayleigh line has been measured for benzene, toluene, fluorobenzene and bromobenzene (at 22°c). The central part of the spectrum was measured at high resolution using a piezoelectric scanned Fabry-Pérot with a maximum free-spectral range of about 20 cm^-1. The entire spectrum was also measured with a monochromator extending the region to 100 cm^-1. The results from the two techniques were combined in order to deduce the correct line shape from which we were able to determine two relaxation times τ1 and τ2.