Nuclear Quadrupole Effect on Rotational Levels of a Molecule with Two Nuclei Having Spins of 52
- 15 June 1966
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 44 (12), 4603-4611
- https://doi.org/10.1063/1.1726678
Abstract
The effect of two equivalent, symmetrically located quadrupolar nuclei of 52 spin on the rotational energy levels of a rigid asymmetric rotor is determined. Matrix elements are derived for the Hamiltonian which describes the quadrupole coupling in the molecule. First-order energy-level corrections for J≦12 have been calculated. Relative intensities for transitions involving J≦5 have likewise been calculated.Keywords
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