A Combined NRVS and DFT Study of FeIVO Model Complexes: A Diagnostic Method for the Elucidation of Non‐Heme Iron Enzyme Intermediates
- 5 November 2008
- journal article
- research article
- Published by Wiley in Angewandte Chemie International Edition
- Vol. 47 (47), 9071-9074
- https://doi.org/10.1002/anie.200803740
Abstract
In the swing of things: FeIVO biomimetic model complexes (see picture, Fe green, O red, N blue, C black) have been characterized using nuclear vibrational resonance spectroscopy. Systematic trends in the low‐energy region reflect equatorial and axial bonding differences that relate to differences in reactivity. These trends have been computationally extended to predict the spectra of putative FeIVO intermediates in non‐heme iron enzymes.Keywords
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