A comparative study of the interaction-induced spectra of liquid CS2
- 10 June 1981
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 43 (2), 307-319
- https://doi.org/10.1080/00268978100101351
Abstract
The ‘forbidden’ Raman spectra of the antisymmetric stretch and bending modes of CS2 are studied on dilution in a series of solvents. The variation of the Raman intensity with concentration supports the conclusion of earlier work—that the interaction-induced polarizability is caused by the action of the re-radiated field gradients from neighbours on the vibrationally modulated quadrupole polarizability. The change in the antisymmetric stretch lineshape shows that the profile of this band is predominantly determined by a resonance energy transfer mechanism.Keywords
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