Trajectory studies of atomic recombination reactions. V. Recombination of bromine atoms
- 15 September 1973
- journal article
- research article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 59 (6), 2974-2976
- https://doi.org/10.1063/1.1680431
Abstract
Recombination of Br atoms in Ar was studied by 3D trajectory calculations between 300 and 1500°K. The recombination path via unstable Br–Ar quasidimers was included in the calculations, which yield recombination rate constants in agreement with experiment within a factor of 2, provided that the ArBr Lennard‐Jones interaction is of the order of 0.5 kcal/mole.Keywords
This publication has 28 references indexed in Scilit:
- Trajectory studies of atomic recombination reactions. IV. Recombination of iodine atomsThe Journal of Chemical Physics, 1973
- Trajectory studies of atomic recombination reactions. III. Energy transfer in bromine-inert gas systemsThe Journal of Chemical Physics, 1973
- Classical dynamics of three-body recombination via the resonance complex mechanismChemical Physics Letters, 1972
- Monte Carlo Trajectory Calculations of the Three-Body Recombination and Dissociation of Diatomic MoleculesThe Journal of Chemical Physics, 1972
- Trajectory Studies of Atomic Recombination Reactions. II. The Energy Transfer Mechanism and Nonequilibrium EffectsThe Journal of Chemical Physics, 1972
- Monte Carlo Trajectory Calculations of the Dissociation of HCl in ArThe Journal of Chemical Physics, 1972
- On the Mechanism of Low-Temperature Termolecular Atomic RecombinationThe Journal of Chemical Physics, 1972
- Trajectory Studies of Atomic Recombination ReactionsThe Journal of Chemical Physics, 1971
- Gas-Phase Recombination of Hydrogen. A Comparison between Theory and ExperimentThe Journal of Chemical Physics, 1971
- Resonance Theory of Termolecular Recombination Kinetics: H+H+M→H2MThe Journal of Chemical Physics, 1969