Chemistry of 1,2-Thiaphosphole 2-Sulfides. II. Reactions of 1,2-Thiaphosphole 2-Sulfides with Some Nucleophiles
- 1 January 1986
- journal article
- research article
- Published by Oxford University Press (OUP) in Bulletin of the Chemical Society of Japan
- Vol. 59 (1), 59-66
- https://doi.org/10.1246/bcsj.59.59
Abstract
5-t-Butyl-1,2-thiaphosphole 2-sulfides reacted with alcohols, thiols, and amines to give the 1,4-adducts, 2-alkoxy-, 2-(p-tolylthio)-, and 2-alkyl(aryl)amino-1,2-thiaphosphol-3-ene 2-sulfides, respectively. However, the reactions of 5-phenyl-1,2-thiaphosphole 2-sulfides with cyclohexyl- and arylamines afforded 1,2,3-dithiaphosphorins.Keywords
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