Paramagnetic Resonance Spectrum of Manganese in CdW $O_{4}$

The paramagnetic resonance spectrum of

{Mn}^{2 +}

in CdW

O_{4}

was measured at 34 kMc/sec at room temperature. The spectrum can be described by the spin Hamiltonian,

H = g β H \cdot S + D [{S_{z}}^{2} + \frac{1}{3} S (S + 1)] + E ({S_{x}}^{2} - {S_{y}}^{2}) + A I \cdot S,

with

g_{z} = 2.001

g_{x} = 2.003

g_{y} = 1.997

| D | = 5.153

kMc/sec,

| E | = 1.395

kMc/sec,

| A_{z} | = 0.246

kMc/sec,

| A_{x} | = 0.242

kMc/sec,

| A_{y} | = 0.259

kMc/sec,

S = \frac{5}{2}

, and

I = \frac{5}{2}

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Paramagnetic Resonance Spectrum of Manganese in CdWO4