99—THE ADSORPTION OF NON-IONIC DYES BY WOOL
- 1 December 1960
- journal article
- research article
- Published by Taylor & Francis in Journal of the Textile Institute Transactions
- Vol. 51 (12), T1342-T1350
- https://doi.org/10.1080/19447026008662568
Abstract
Linear isotherms have been obtained on wool, at 40°, 60° and 80°C, with derivatives of azobenzene. In most cases with truly non-ionic dyes, the plot of –δμ°/RT against 1/T also appears to be linear, indicating a constant heat of dyeing. With the weakly acidic 4-carboxy- and 4-sulphonamido-azobenzene, and the weakly basic 2,4-diaminoazobenzene, the heat of dyeing is not constant, probably owing to variation in the extent of ionization at different temperatures. The most soluble of the truly non-ionic dyes examined also showed a variable heat of dyeing. Non-ionic dyes have low affinity for wool and, consequently, low fibre saturation values.Keywords
This publication has 10 references indexed in Scilit:
- Some Aspects of the Dyeing of Acrylic Fibres, with particular reference to the Pack‐dyeing of CourtelleJournal of the Society of Dyers and Colourists, 1958
- The Dyeing of Cellulose Acetate with Disperse Dyes: VI— Affinities, Heats of Dyeing, and Heats of SolutionJournal of the Society of Dyers and Colourists, 1957
- The Disperse Dyes — Their Development and ApplicationJournal of the Society of Dyers and Colourists, 1956
- The Dyeing of Acetate Rayon with Disperse Dyes IVndashAdsorption IsothermsJournal of the Society of Dyers and Colourists, 1955
- The Dyeing of Cellulose Acetate with Non‐ionic DyesJournal of the Society of Dyers and Colourists, 1954
- THE RELATION OF PHYSICAL PROPERTIES OF CARCINOGENS TO THEIR ACTIVITY. I. THE BASICITY OF ALKYLATED 4-AMINOAZOBENZENE DYES1The Journal of Organic Chemistry, 1954
- The dyeing of synthetic polypeptidesDiscussions of the Faraday Society, 1954
- The Effect of Solvent on Equilibrium and Rate Constants. II. The Measurement and Correlation of Acid Dissociation Constants of Anilinium and Ammonium Salts in the System Ethanol—Water1,2aJournal of the American Chemical Society, 1953
- The Combination of Wool with Acids–a Quantitative Interpretation in terms of the Donnan Theory of Membrane Equilibrium*Journal of the Society of Dyers and Colourists, 1949
- Derivatives of p-aminobenzenesulphonamide in the treatment of streptococcal infection in miceBiochemical Journal, 1937