Hydrogen desorption and adsorption measurements on graphite nanofibers

Abstract

Graphite nanofibers were synthesized and their hydrogen desorption and adsorption properties are reported for 77 and 300 K. Catalysts were made by several different methods including chemical routes, mechanical alloying, and gas condensation. The nanofibers were grown by passing ethylene and ${\mathrm{H}}_2$ gases over the catalysts at $\text{600\hspace{0.05em}°}\mathrm{C}.$ Hydrogen desorption and adsorption were measured using a volumetric analysis Sieverts’ apparatus, and the graphite nanofibers were characterized by transmission electron microscopy and Brunauer–Emmett–Teller surface area analysis. The absolute level of hydrogen desorption measured from these materials was typically less than the 0.01 H/C atom, comparable to other forms of carbon.