Palladium Mesowire Arrays for Fast Hydrogen Sensors and Hydrogen-Actuated Switches

Abstract

Arrays of mesoscopic palladium wires prepared by electrodeposition form the basis for hydrogen sensors and hydrogen-actuated switches that exhibit a response time ranging from 20 ms to 5 s, depending on the hydrogen concentration. These devices were constructed by electrodepositing palladium mesowires on a highly oriented pyrolytic graphite surface and then transferring these mesowires to a cyanoacrylate film supported on a glass slide. The application of silver contacts to the ends of 10−100 mesowires, arrayed electrically in parallel, produced sensors and switches that exhibited a high conductivity state in the presence of hydrogen and a low conductivity state in the absence of hydrogen. After an initial exposure to hydrogen, 15−50 nanoscopic gaps are formed in each mesowire. These nanoscopic gaps or “break junctions” close in the presence of hydrogen gas and reopen in its absence as hydrogen is reversibly occluded by the palladium grains in each wire, and the palladium lattice expands and contracts by several percent. The change in resistance for sensors and switches was related to the hydrogen concentration over a range from 1 to 10%.