Identification of the structure of the3T1g(I) ←3A2gband in the Ni(H2O)6++complex
- 1 January 1975
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 29 (1), 279-299
- https://doi.org/10.1080/00268977500100191
Abstract
A detailed study of the low temperature absorption spectra of some 16 molecular crystals containing Ni(H2O)6 ++ has allowed us to identify the electronic and vibrational origins of the ‘red’ absorption band. A complete band contour analysis has been performed, which makes possible a discussion of the crossing of the 1Γ3 and 3Γ3 levels.Keywords
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