Semiclassical treatment of atom-asymmetric rotor collisions; rotational excitation of formaldehyde at low energies

Abstract

The formalism necessary for the application of ``classical S‐matrix'' theory to collisions of an atom with a rigid asymmetric rotor is derived. This is applied to rotational excitation of formaldehyde by H₂ (taken to be spherically symmetric) at energies from 10 to 15°K. Classical Monte Carlo trajectory calculations were also carried out for the same system in the energy range 10–40°K. The results support the proposal of Townes and Cheung that a collisional mechanism is responsible for the 1₁₁ →1₁₀ anomalous absorption of formaldehyde in cool interstellar dust clouds.