Stereoselective construction of nitrile-substituted cyclopropanes
- 7 February 2008
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 10,p. 1238-1240
- https://doi.org/10.1039/b719175h
Abstract
Nitrile-substituted cyclopropanes are readily synthesized in a stereocontrolled fashion from the intermolecular cyclopropanation between 2-diazo-2-phenylacetonitrile and electron-rich olefins, catalyzed by the chiral dirhodium complex, Rh2(S-PTAD)4.Keywords
This publication has 33 references indexed in Scilit:
- Trapping of Oxonium Ylide with Isatins: Efficient and Stereoselective Construction of Adjacent Quaternary Carbon CentersOrganic Letters, 2007
- Copper-Catalyzed Asymmetric N−H Insertion Reactions: Couplings of Diazo Compounds with Carbamates to Generate α-Amino AcidsJournal of the American Chemical Society, 2007
- Enhancement of Cyclopropanation Chemistry in the Silver-Catalyzed Reactions of AryldiazoacetatesJournal of the American Chemical Society, 2007
- Investigation into Factors Influencing Stereoselectivity in the Reactions of Heterocycles with Donor−Acceptor-Substituted Rhodium CarbenoidsThe Journal of Organic Chemistry, 2006
- Catalytic Enantioselective O−H Insertion ReactionsJournal of the American Chemical Society, 2006
- Highly Enantio‐ and Diastereoselective Construction of 1,2‐Disubstituted Cyclopentane Compounds by Dirhodium(II) Tetrakis[N‐phthaloyl‐(S)‐tert‐leucinate]‐Catalyzed C-H Insertion Reactions of α‐Diazo EstersAdvanced Synthesis & Catalysis, 2005
- Rhodium‐Catalyzed Asymmetric Intramolecular Cyclopropanation of Substituted Allylic CyanodiazoacetatesAdvanced Synthesis & Catalysis, 2005
- Highly Enantioselective Cyclopropanation of Styrenes and Diazoacetates Catalyzed by 3-Oxobutylideneaminatocobalt(II) Complexes, Part 2. Semiempirical Analysis of Diastereo and EnantioselectivitiesBulletin of the Chemical Society of Japan, 2001
- Dirhodium Tetra(N-arylsulfonylprolinates) as Chiral Catalysts For Asymmetric Transformations of Vinyl- and AryldiazoacetatesEuropean Journal of Organic Chemistry, 1999
- The sym-Triphenylcyclopropenyl Cation, a Novel Aromatic System1Journal of the American Chemical Society, 1958