n-CuInSe2/polysulfide photoelectrochemical solar cells

Abstract
We report that n‐type single crystals of n‐CuInSe2 in aqueous polysulfide solution exhibit high quantum efficiencies of 0.8–0.9 in the wavelength region between 600–1150 nm when used as photoanodes in photoelectrochemical cells. Photocurrents of 28 mA/cm2 were measured on a ’’winter’’ day in Rehovot (71 mW/cm2) which corresponds to 40 mA/cm2 under AM1 (Air Mass 1) conditions (100‐mW/cm2 sunlight). Stability tests of n‐CuInSe2 photoanodes (20 000‐C/cm2 photocharge passage) at short circuit current densities of 40 mA/cm2 have shown no deterioration whatsoever of the measured photocurrents.