X-ray Crystal and NMR Structure of a Highly Reactive Bidentate 1,2-Diamine−OsO4 Complex, Formally a 20-Electron Outer Valence Shell Species. Mechanistic Implications for the 1,2-Diamine-Accelerated Dihydroxylation of Olefins by OsO4
- 1 January 1996
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 118 (33), 7851-7852
- https://doi.org/10.1021/ja960536d
Abstract
No abstract availableThis publication has 11 references indexed in Scilit:
- Kinetic Investigations Provide Additional Evidence That an Enzyme-like Binding Pocket Is Crucial for High Enantioselectivity in the Bis-Cinchona Alkaloid Catalyzed Asymmetric Dihydroxylation of OlefinsJournal of the American Chemical Society, 1996
- Catalytic Asymmetric DihydroxylationChemical Reviews, 1994
- Asymmetric dihydroxylation of olefins with a simple chiral ligandThe Journal of Organic Chemistry, 1993
- Asymmetrized trils (hydroxymethyl)methane as a highly stereodivergent chiral building block: preparation of all four stereoisomers of protected 2-hydroxymethyl-1,3-butanediolTetrahedron Letters, 1990
- Enantioselective vicinal hydroxylation of terminal and E-1,2-disubstituted olefins by a chiral complex of osmium tetroxide. An effective controller system and a rational mechanistic modelJournal of the American Chemical Society, 1989
- Asymmetric dihydroxylation of alkenes with osmium tetroxide: chiral N,N′-dialkyl-2,2′-bipyrrolidine complexJournal of the Chemical Society, Chemical Communications, 1989
- Enantioface differentiation in cis dihydroxylation of carbon-carbon double bonds by osmium tetroxide using a chiral diamine with D2 symmetryJournal of the American Chemical Society, 1987
- Asymmetric oxidation of olefins to vicinal diols with osmium tetroxideTetrahedron Letters, 1986
- ASYMMETRIC OXIDATION OF OLEFINS WITH OSMIUM TETROXIDE COORDINATED BY CHIRAL DIAMINES DERIVED FROM L-TARTARIC ACIDChemistry Letters, 1986
- Partial coordination in amine adducts of osmium Tetraoxide: X-ray molecular structure of quinuclidinetetraoxo-osmium(VIII)Inorganica Chimica Acta, 1978