Vibration rotation spectroscopy of open-shell molecular ions
- 1 May 1986
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 58 (1), 85-95
- https://doi.org/10.1080/00268978600101001
Abstract
We report rotationally resolved vibrational spectra of the DCL+ molecular ion for ν = 1 ← 0 to ν = 7 ← 6 with a Faraday-L.M.R. spectrometer. The ions were generated in a d.c.-excited discharge of the anomalous type near 2 torr total pressure. A small probe modulation coil allows spatial resolution of the concentration profile along the discharge. Comparisons of such profiles between anomalous and normal discharge conditions are presented. Spectroscopic constants for DCl+ X 2Π3/2 are reported.Keywords
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