NMR Study of Compositional Inhomogeneities in Sputtered Co-Cr Films

Abstract
The development of compositional inhomogeneities in sputtered Co-22 at.% Cr films is studied as a function of substrate temperature using the spin-echo 59Co-NMR technique. It is observed that a highly Co-rich component grows as the substrate temperature increases from 30°C to 400°C. The Cr content of the Co-rich part in the film deposited at 400°C is estimated to be as low as 5-7 at.%. The results are consistent with the appearance of a clearly striped compositional microstructure which suggests compositional separation.