Reactions of 1,2,4-trichlorotrifluorobenzene with nucleophiles
- 1 January 2016
- journal article
- Published by Pleiades Publishing Ltd in Russian Journal of Organic Chemistry
- Vol. 52 (1), 25-31
- https://doi.org/10.1134/s107042801601005x
Abstract
1,2,4-Trichlorotrifluorobenzene reacted with potassium hydrogen sulfide, potassium hydroxide, sodium isopropoxide, liquid ammonia, and ethyl cyanoacetate via nucleophilic substitution of one fluorine atom with predominant formation of the isomer in which the new substituent replaced fluorine atom in the 5-position.Keywords
This publication has 10 references indexed in Scilit:
- Triazidation of 2,4,6-trifluorobenzenesJournal of Fluorine Chemistry, 2013
- Oxyanion Steering and CH−π Interactions as Key Elements in an N-Heterocyclic Carbene-Catalyzed [4 + 2] CycloadditionJournal of the American Chemical Society, 2012
- Synthesis of 1,2-dichlorotetrafluoro- and 1,2,4-trichlorotrifluorobenzenesRussian Journal of Organic Chemistry, 2012
- Selective mono-and diamination of polyfluorinated benzenes and pyridines with liquid ammoniaRussian Chemical Bulletin, 2007
- Stable Nickel Catalysts for Fast Norbornene Polymerization: Tuning ReactivityEuropean Journal of Inorganic Chemistry, 2005
- Catalytic Fluorodechlorination of Polychlorofluorobenzenes with Potassium FluorideRussian Journal of Organic Chemistry, 2002
- 3,5-dichlorotrifluorophenyl complexes, aryl derivatives with simple 19F NMR structural probes. The synthesis of general precursors for Pd- and Pt complexesJournal of Organometallic Chemistry, 1998
- The Grignard Reagents Prepared from Perchlorofluorobenzenes and Their ReactionsNippon kagaku zassi, 1968
- Preparation of hexafluorobenzene from hexachlorobenzeneRussian Chemical Bulletin, 1963
- Synthesis of PolyfluorobenzenesThe Journal of Organic Chemistry, 1962