The Spectra of Strontium Hydride

Abstract
New SrH band systems photographed at high dispersion include: (1) an abbreviated CΣ2NΣ2 system with (0,0) band head at 3808A, (2) a many-lined DΣ2NΣ2 system between 5000A and 6700A, (3) an EΠ2NΣ2 system consisting of a Δv=0 sequence only with the (0,0) band at 5323A. The (0,0) and (0,1) C bands have three violent perturbations and a sharp cut-off due to predissociation at K=19. The form and magnitude of the perturbations are computed. Quantum analyses give B0=3.930 and D0=9.31×104 for the C state, B1=3.56 for the normal state. Quantum assignments of the lines of the six principal branches of the (0,0) band of the E system are presented. For the E state A=117, B*0, 12=3.6388, B*0, +12=3.8687 and perturbations at small J values distort the Λ-doubling curve for the Π122 state.

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