Photogeneration of ions via delocalized charge transfer states. I. Xe2H+ and Xe2D+ in solid Xe
- 15 April 1992
- journal article
- Published by AIP Publishing in The Journal of Chemical Physics
- Vol. 96 (8), 5630-5635
- https://doi.org/10.1063/1.462687
Abstract
Delocalized charge‐transfer excitations in solid xenon multiply doped with atomic halogens (I, Br, Cl) and hydrogen are demonstrated to lead to charge separation by trapping of the positive charge. As evidence of such a concept we present the first vibrational spectra of Xe2H+ and Xe2D+, which are believed to be vibrationally bound ions.Keywords
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