Abstract
Theoretical expressions that include the effect of electron exchange are given for ML electron-capture ratios; the results are presented in a form that makes clear the physical origin of the exchange corrections. Accurate values for ML ratios both with and without exchange corrections are tabulated for Z between 13 and 37; these numerical results were calculated using the analytic Hartree-Fock wave functions of Watson and Freeman. The exchange correction for Z greater than or equal to 38 has been estimated by a least squares extrapolation of the correction for lower Z values. The effect of electron exchange on electron capture to positron-emission ratios is also discussed. The exchange-corrected theoretical ML ratio for Ge7132 is 0.173, in disagreement with the recent measurement of Manduchi and Zannoni. It is suggested that some additional precision measurements of ML ratios be performed in order to clarify this discrepancy between theory and experiment.

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