X-ray emission studies of the electron structure of ni atoms in nickel-aluminium alloys
- 1 May 1975
- journal article
- Published by IOP Publishing in Journal of Physics F: Metal Physics
- Vol. 5 (5), 837-842
- https://doi.org/10.1088/0305-4608/5/5/016
Abstract
New measurements of the main nik emission lines are presented for nickel-aluminium alloys with up to 50 at% al. The shifts of the nikalpha/sub 1/ line of the alloys are found to be negative with respect to pure nickel, contrary to previous measurements by nemoshkalenko et al. (see abstr. A41614 of 1971). In addition to a possible charge transfer between the constituent atoms, the importance of the crystallographic phase and order is emphasized in the interpretation of the spectra. Complete filling of the d band in the nial compound is not supported by the results.Keywords
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