Titanium Trichloride Reactions: Dehalogenation
- 1 January 1973
- journal article
- research article
- Published by Taylor & Francis in Synthetic Communications
- Vol. 3 (3), 237-239
- https://doi.org/10.1080/00397917308062043
Abstract
We have recently established preparative procedures for titanium(III) reduction of sulfoxides to sulfides1 and nitroarenes to amines.2 In continuation of this program which is aimed at exploring the synthetic potential of titanium(III) ion, we have found that α-haloketones undergo facile dehalogenation upon treatment with titanium trichloride.Keywords
This publication has 12 references indexed in Scilit:
- Titanium (III) Reduction of SulfoxidesSynthetic Communications, 1973
- Reduction of α-haloketones with lithium iodide and boron trifluorideTetrahedron Letters, 1971
- Mild procedure for transforming nitro groups into carbonyls. Application to the synthesis of cis-jasmoneJournal of the American Chemical Society, 1971
- Stereochemistry of the zinc-acetic acid debromination of .alpha.-bromocamphorThe Journal of Organic Chemistry, 1971
- The reduction of oximes with tervalent titanium, a mild deoximation procedure and the partial synthesis of erythromycylamine.Tetrahedron Letters, 1971
- Reactions of diphenylphosphine with .alpha.-substituted ketones. Dehalogenation and demesylation procedureThe Journal of Organic Chemistry, 1969
- The Reduction of Organic Compounds with Chromium(II) SaltsAngewandte Chemie International Edition in English, 1968
- Reduction of Alkyl Halides by Organotin Hydrides1, 2The Journal of Organic Chemistry, 1963
- The reaction of α-bromoketones with triphenylphosphine - I: A novel debromination reactionTetrahedron Letters, 1962
- The catalytic action of metal salts on the borohydride reduction of α-bromoketoneTetrahedron Letters, 1961