Effects of crystallite size in PbTiO3 thin films

Abstract
The lattice constants of tetragonal PbTiO3 grown by organometallic chemical vapor deposition, vary with average crystallite size in the thin film as determined from line broadening in x‐ray diffraction patterns. The a‐ and c‐lattice constants become equal when the average crystallite size decreases to below ∼5 nm. These data agree with the change in lattice constants as a function of average crystallite size found recently for submicron PbTiO3 powder.

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