The conformations of triostin A in solution
- 1 January 1979
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Journal of the Chemical Society, Perkin Transactions 1
- No. 5,p. 1313-1321
- https://doi.org/10.1039/p19790001313
Abstract
The two symmetrical conformations of triostin A in deuteriochloroform have been investigated by 1H n.m.r. spectroscopy. The occurrence of two conformations is rationalised as resulting from the reversal of chirality of the disulphide bond, which is postulated to exist as a rapidly interconverting mixture of several rotameric states. Analysis of the spectrum of the least polar conformer is consistent with the presence of an intramolecular hydrogen bond.This publication has 5 references indexed in Scilit:
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