ROLE OF HYDROGEN IN POLARIZATION REVERSAL OF FERROELECTRIC Ba2NaNb5O15

Abstract
By field‐annealing barium sodium niobate crystals in the presence of H2O and D2O vapor it is established that protons diffuse into the crystals. As a result of this diffusion, the crystal resistivity is found to increase by a factor of ∼2×103. It is concluded that diffusion of protons into ferroelectric barium sodium niobate and other high‐temperature ferroelectrics is necessary before the crystal dipole moment can be freely reversed by an external electric field.