Chemisorption-Site Geometry from Polarized Photoemission: Si(111)Cl and Ge(111)Cl
- 13 December 1976
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 37 (24), 1632-1635
- https://doi.org/10.1103/physrevlett.37.1632
Abstract
The chemisorption-site geometries for chlorine on cleaved Si(111) 2×1 and Ge(111) 2×1 surfaces have been determined by comparing detailed pseudopotential calculations with energy distribution spectra and polarization selection rules of photoemission spectroscopy. Strong -symmetry polarization effects observed in photoemission allow us to determine that on Si(111) the correct geometry is a onefold covalent site while on Ge(111) the Cl is in a threefold coordinated ionic site.
Keywords
This publication has 16 references indexed in Scilit:
- Determination of the state of hybridization of unsaturated hydrocarbons chemisorbed on nickelPhysical Review B, 1976
- Anisotropic photoemission and chemisorption-bond geometry on Ge(111) and Si(111) surfacesSurface Science, 1975
- Si(111): Si—A Simple New Surface PhasePhysical Review Letters, 1975
- Chemisorption of atomic hydrogen on the silicon (111) 7 × 7 surfacePhysical Review B, 1975
- Self-consistent pseudopotential calculations for Si (111) surfaces: Unreconstructed (1×1) and reconstructed (2×1) model structuresPhysical Review B, 1975
- Interpretation of the photoelectron spectra of molecularly adsorbed COSolid State Communications, 1975
- Self-Consistent Quantum Theory of Chemisorption: H on Si(111)Physical Review Letters, 1975
- Surface Photoelectric Effect and Orbital Symmetry: Evidence for Anomalous Dielectric PropertiesPhysical Review Letters, 1975
- Electron orbital energies of oxygen adsorbed on silicon surfaces and of silicon dioxidePhysical Review B, 1974
- Hydrogen adsorption and surface structures of siliconSurface Science, 1974